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1.
《International Journal of Hydrogen Energy》2022,47(65):27973-27985
Metal-support interaction and catalyst pretreatment are important for industrial catalysis. This work investigated the effect of supports (SiO2, CeO2, TiO2 and ZrO2) for Cu–Pd catalyst with high Cu/Pd ratio (Cu/Pd = 33.5) regarding catalyst cost, and the reduction temperatures of 350 °C and 550 °C were compared. The activity based on catalyst weight follows the order of Si > Ce > Zr > Ti when reduced at 350 °C. The reduction temperature leads to the surface reconstruction over the SiO2, CeO2 and TiO2 catalysts, while results in phase transition over Cu–Pd/ZrO2. The effect of reduction temperature on catalytic performance is prominent for the SiO2 and ZrO2 supported catalysts but not for the CeO2 and TiO2 ones. Among the investigated catalysts, Zr-350 exhibits the highest methanol yield. This work reveals the importance of the supports and pretreatment conditions on the physical-chemical properties and the catalytic performance of the Cu–Pd bimetallic catalysts. 相似文献
2.
Bin Zhang Meng Zhang Yu Li Huansheng Cheng Jianming Zheng 《Ceramics International》2019,45(3):3081-3087
Proton induced X-ray emission (PIXE) technique and factor analysis were used to study the recovery of making-technology of Chinese Longquan celadon made in the late Southern Song Dynasty (1127–1279 CE). Based on factor analysis, for the raw material for body and the recipe for glaze, there is a close but slightly different relationship between these Longquan celadons unearthed from the core area of Dayao and the non-core area, despite all the Longquan celadons belong to the high-calcium-glaze system. The chemical compositions of most of the tentative body and glaze samples are very close to those of Longquan celadons unearthed from the core area of Dayao and the non-core area. This study can provide a guidance for recovery of making-technology of Longquan celandon. 相似文献
3.
Alinda Samsuri Mohd Nor Latif Mohd Razali Shamsuddin Fairous Salleh Maratun Najiha Abu Tahari Tengku Shafazila Tengku Saharuddin Norliza Dzakaria Mohd Ambar Yarmo 《International Journal of Hydrogen Energy》2021,46(48):24831-24844
Temperature programmed reduction (TPR) analysis was applied to investigate the chemical reduction progression behavior of molybdenum oxide (MoO3) catalyst. The composition and morphology of the reduced phases were characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). The reduction progression of MoO3 catalyst was attained with different reductant types and concentration (10% H2/N2, 10% and 20% CO/N2 (%, v/v)). Two different modes of reduction process were applied. The first approach of reduction involved non-isothermal mode reduction up to 700 °C, while the second approach of reduction involved the isothermal mode reduction for 60 min at 700 °C. Hydrogen temperature programmed reduction (H2-TPR) results showed the reduction progression of three-stage reduction of MoO3 (Mo6+ → Mo5+ → Mo4+ → Mo0) with Mo5+ and Mo4+. XRD analysis confirmed the formation of Mo4O11 phase as an intermediate phase followed by MoO2 phase. After 60 min of isothermal reduction, peaks of metallic molybdenum (Mo) appeared. Whereas, FESEM analysis showed porous crater-like structure on the surface cracks of MoO2 layer which led to the growth of Mo phase. Meanwhile, the reduction of MoO3 catalyst in 10% carbon monoxide (CO) showed the formation of unstable intermediate phase of Mo9O26 at the early stage of reduction. Furthermore, by increasing 20% CO led to the carburization of MoO2 phase, resulted in the formation of Mo2C rather than the formation of metallic Mo, as confirmed by XPS analysis. Therefore, the presented study shows that hydrogen gave better reducibility due to smaller molecular size, which contributed to high diffusion rate and achieved deeper penetration into the MoO3 catalyst compared to carbon monoxide reductant. Hence, the reduction of MoO3 in carbon monoxide atmosphere promoted the formation of Mo2C which was in agreement with the thermodynamic assessment. 相似文献
4.
简要介绍世界几种主要薄板坯连铸工艺。着重叙述应用大型通用商业软件MSC.MARC。模拟液芯压下时铸坯的变形,确定最佳压下方案的有限元分析,液芯压下应该在结晶器出口处及二冷区扇形段开始部分进行,这样能减小铸坯的应变。 相似文献
5.
本文研究了在秦山核电厂批平均卸料燃耗深度超过原定限值的情况下,为保证电厂的安全运行对DNBR限值进行重新确认的问题。研究过程中,综合考虑了由燃耗加深所引起的核焓升因子的变化和棒弯曲这两种效应对DNBR限值的影响。结果表明,对秦山核电厂而言,在批平均卸料燃耗超过原定限值的情况下,维持原DNBR限值不变仍是安全可行的。 相似文献
6.
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
7.
Cherng-Min MaAuthor Vitae 《Pattern recognition》2003,36(8):1775-1782
Generally, a reduction operation (e.g., thinning and shrinking) on 3D binary images can be represented as a set of reduction templates where every object voxel of the image satisfying any template is turned to a background voxel. Generally, it is rather difficult, error-prone and time-consuming for verifying the topological soundness of a 3D parallel reduction operation. This paper proposes sufficient conditions of time complexity O(n) for verifying the topological soundness of 3D parallel 6-subiteration reduction operations of n templates where such a kind of 3D reduction operations is performed alternatively from the six orthogonal directions to turn object voxels to background voxels. By such sufficient conditions, the topology soundness of a 3D 6-subiteration parallel reduction operation can be verified by checking each and every of its templates. 相似文献
8.
蒋光祖 《上海电机学院学报》2003,6(4):9-10
推导了变压器二次负载电压的计算公式,建议由此公式代替以往原理书中惯用的近似公式。利用此公式绘制和分析了不同功率因数额定负载时的相量轨迹图。 相似文献
9.
27例乙型血友病患者Ⅸ因子基因突变研究 总被引:1,自引:0,他引:1
采用PCR(聚合酶链反应)及GAWTS(GenomicAmplificationwithTranscriptsSequencing)技术,研究了江苏、湖北、山东、广东、福建、宁夏六省区27例乙型血友病患者及其家系成员FⅨ(九因子)基因各2.2Kb DNA序列。在2l例中发现20种不同类型的突变。其中12种是未曾报道的新突变。38%的突变发生在CpG二核苷致序列上,进一步证实了CpG确系突变热点。同时检出6例女性为致病基因携带者。对开展基因产前诊断及优生优育等,具有重要意义。 相似文献
10.
设计并研制成功适合人的眼睛安全测距应用的InGaAs雪崩光电二极管(APD)。器件直径为200μm,工作在21℃,1540nm波长时响应为0.64A/W,典型暗电流和噪声因子分别为30nA和6.5。介绍了该器件的工作原理,设计和制作工艺。 相似文献